Any gas can be converted into a liquid by simple compression, unless its temperature is below critical. Therefore, the division of substances into liquids and gases is largely conditional. The substances that we are used to considering as gases simply have very low critical temperatures and therefore cannot be in a liquid state at temperatures close to room temperature. On the contrary, the substances we classify as liquids have high critical temperatures (see table in §
).
All gases that make up the air (except carbon dioxide) have low critical temperatures. Their liquefaction therefore requires deep cooling.
There are many types of machines for producing liquid gases, in particular liquid air.
In modern industrial plants, significant cooling and liquefaction of gases is achieved by expansion under thermal insulation conditions.